Dataset for waste tire and constituent polymers pyrolysis on Me/NT-Ti (Me = Pd, Au, Pt)

Registro completo

Título

Dataset for waste tire and constituent polymers pyrolysis on Me/NT-Ti (Me = Pd, Au, Pt)

Autor(es)

Arteaga Pérez, Luis E.; Osorio Vargas, Paula; Smith-Azócar, Beatriz; Medina, Francisco; Campos, Cristian H.

Afiliación(es) del/de los autor(es)

Arteaga-Pérez, Luis E. Universidad del Bío-Bío. Facultad de Ingeniería. Departamento de Ingeniería en Maderas. Laboratory of Thermal and Catalytic Processes; Chile
Osorio Vargas, Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. J.J. Ronco”. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. J.J. Ronco”. Comisión de Investigaciones Científicas de la Provincia de Buenos Aires. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. J.J. Ronco”; Argentina
Smith-Azócar, Beatriz. Universidad del Bío-Bío; Chile
Medina, Francisco. Universidad del Bío-Bío; Chile
Campos, Cristian H. Universidad de Concepción. Facultad de Ciencias Químicas. Departamento de Físico-Química; Chile

Resumen

This dataset includes results on the thermal characterization of waste tires by thermogravimetric analysis. In addition here we report a complete dataset on the analytical pyrolysis (Py-GC/MS) experiments of WT in the presence of different catalysts. The data is complementary to a published paper, thus a complete description of the materials, methods and equipments used to obtain this dataset is provided in those papers. The experiments were done for waste tires coming from light vehicles, and three metals Pd, Pt, Au deposited on titanate nanotubes (NT-Ti) were used as catalysts for selectively produce valuable chemicals. Experimental factors were the metal nature of the catalyst and the pyrolysis temperature (400 – 450ºC). Moreover, the pyrolysis was investigated for three individual polymers (polyisoprene, butadiene, and styrene-butadiene) to establish possible reaction routes describing the role of metals in the pyrolysis reaction map and product distribution. Three folders are provided here: 1- Raw datafile for TGA of WT recorded in N2 flow between 20 and 650ºC at 10 ºC/min. 2- Datafiles for TurboMass software v5.4 (Perkin Elmer, 2017) with the results of all pyrolytic experiments ordered by materials, temperatures and catalysts nature. 3- Excel files with the retention time, peak area, peak height, among other chromatographic results from the Py-GC/MS.
Facultad de Ciencias Exactas
Centro de Investigación y Desarrollo en Ciencias Aplicadas

Año de publicación

2021

Idioma

inglés

Formato (Tipo MIME)

application/zip
The data was measured in a micro-pyrolysis reactor (CDS5200, CDS Analytical Co Ltd.) coupled to a gas chromatograph (Clarus 690, Perkin Emer) equipped with a quadrupole mass detector (SQ8, Perkin Emer). The waste tires were characterized in an elemental analyser (CHNS 628, Leco) and thermogravimetric analysis (Netzsch, model STA 409 PC). Compound identification was done by comparison with the National Institute of Standards and Technology database (NIST, v2016) with the software TurboMass™ v5.4.

Clasificación temática de acuerdo a la FORD

Ciencias químicas

Materia

Ciencias Exactas; Química; Catalysis; Thermogravimetric Analysis; Tyre; Analytical Pyrolysis;

Condiciones de uso

Disponible en acceso abierto bajo licencia Creative Commons http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0)

Repositorio digital

SEDICI (UNLP) - Universidad Nacional de La Plata

Identificador alternativo

https://doi.org/10.17632/m72tyjb8nr.1

Publicación referenciada

http://hdl.handle.net/hdl/10915/154475

Publicación referenciada

http://hdl.handle.net/hdl/10915/154472